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Depletion gilding is a method for producing a layer of nearly pure gold on an object made of gold alloy by removing the other metals from its surface. It is sometimes referred to as a "surface enrichment" process.〔The Surface Enrichment of Carat Gold Alloys - Depletion Gilding. Mark Grimwade in Gold Technology, Issue 26; July 1999.〕 ==Process== Most gilding methods are additive, that is, they deposit gold that was not there before onto the surface of an object. By contrast, depletion gilding is a subtractive process whereby material is removed to increase the purity of gold that is already present on an object's surface. Essentially, depletion gilding produces a high-purity gold surface by removing everything that is not gold. More specifically, other metals are etched away from the surface of an object composed of a gold alloy by the use of acids or salts, often in combination with heat. Of course, since no gold is actually added, only an object made of an alloy that already contains at least some gold can be depletion gilded. Depletion gilding relies on the fact that gold is highly resistant to oxidation or corrosion by most common chemicals, whereas many other metals are not. Depletion gilding is most often used to treat alloys of gold with copper and/or silver. Unlike gold, both copper and silver readily react with a variety of chemicals. For example, nitric acid is effective as an etching agent for both copper and silver. Under the proper circumstances, even ordinary table salt (sodium chloride) will react with either metal. The object to be gilded is coated, immersed, or packed in a suitable acid or salt. These chemicals then attack the metallic copper and silver in the object's surface, transforming it to various copper and silver compounds. The object is usually heated to make the etching process more efficient. Regardless, the resulting copper and silver compounds can be removed from the object's surface by a number of processes. Washing, chemical leaching, heating, or even physical absorption by porous materials such as brick dust have all been used. However, the relatively inert gold remains behind, unaffected. The result is a thin layer of nearly pure gold on the surface of the original object. There is no well-defined minimum gold content required to successfully depletion gild an object. However, as a practical matter, the less gold that is present, the more other material must be etched away to produce the desired surface appearance. In addition, the removal of the other metals usually leaves the surface covered with microscopic voids and pits. This can make the surface soft and "spongy" with a dull or matte appearance. This effect becomes more pronounced as more base metal is removed. For this reason, most depletion gilded objects are burnished to make their surfaces more durable and give them a more attractive polished finish. Like other gilding processes, depletion gilding provides a way to produce the appearance of pure gold without its disadvantages. Most obviously, the cost and rarity of gold limits the use of the pure metal, especially in large objects. In addition, pure gold is both extremely soft and very dense, two factors that limit its utility. By producing a layer of gold over a layer of copper or other metal, objects can be made that are lighter, sturdier, and cheaper while still appearing to be nearly pure gold. ==Variations== The term depletion gilding usually refers to the production of a layer of gold. However, it can also be used to produce a layer that is an alloy of gold and silver, sometimes referred to as electrum. Certain chemicals, such as oxalic acid, attack copper but do not affect either silver or gold. Using such a chemical, it is possible to remove only the copper in an alloy, leaving both silver and the gold behind. Thus, if the original object is composed of copper, silver, and gold, it can be given a gold surface by removing both silver and copper, or an electrum surface by removing only the copper. Likewise, with an appropriate chemical, a layer of nearly pure silver can be produced on an object made of copper and silver. For instance, sterling silver can be depleted - 'depletion silvering' - to produce a fine silver surface, perhaps as preamble to application of gold, as in the Keum-boo technique. However, in the majority of cases depletion gilding is in fact used to produce a gold finish, rather than one of electrum or silver. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「depletion gilding」の詳細全文を読む スポンサード リンク
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